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The Effect of Different Detergents on
Stain Removal from Cotton Cloth
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Researched by Michelle B.
2005-06
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PURPOSE
The purpose of this experiment was to compare the effectiveness of
different brands of detergent in removing stains from cotton cloth.
I became interested in this idea when I got stains on my white cotton
t-shirts. My mom washed them but the detergent she used didn’t always
get the stain out. T-shirts are expensive to replace and I
wondered if I could find a better detergent.
The information gained from this experiment would help homemakers,
laundry services, hotels, hospitals, and others make better choices on
which detergent to buy.
HYPOTHESIS
My hypothesis was that Tide would remove the test stains most
effectively.
I based my hypothesis on the recent studies in “Consumer Reports”
(October 2005, page 6) that showed Tide was the most reliable
detergent/stain remover.
I also based my hypothesis on a study by Carrie Jo Nevue, a former 7th
grade student. She also tested detergents and concluded that Tide
detergent worked the best. Terri Bauman, a homemaker for 21
years, also believes that Tide Detergent works the best in stain
removal.
EXPERIMENT
DESIGN
The constants in this study were:
• The amount of detergent used (100 ml.)
• The temperature of water used
• The ingredients in the stain: Chocolate syrup,
black coffee, purple grape juice, ravioli sauce, ketchup and mustard.
• The method of washing in-a washing machine.
• The method of drying-in a drying machine.
The manipulated variable was the type of detergent.
The responding variable was whiteness of cloth.
To measure the responding variable, I used a Hunter Reflectance
Spectrophotometer (Colorimeter) to determine the “L” value
(brightness.)
MATERIALS
| QUANTITY |
ITEM DESCRIPTION |
1
|
Colorimeter |
1
|
Washing Machine |
1
|
Drying Machine |
100 ml
|
Ketchup |
| 100 ml |
Mustard |
| 100 ml |
Purple Grape Juice |
| 100 ml |
Ravioli Sauce |
1
|
Plastic Spatula |
| 1 |
Large Mixing Bowl |
| 100 ml |
Tide |
| 100 ml |
All |
| 100 ml |
Arm & Hammer |
48
|
10 x 10 cm squares of 100%
White Cotton |
1
|
Pair of Scissors |
100 ml
|
Black Coffee |
100 ml
|
Chocolate syrup |
PROCEDURES
1. Buy white 100% cotton fabric from a fabric store
2. Wash fabric three times in washing machine to
remove factory treatment
3. Lay out the material and cut the cotton into
49 10 cm X 10 cm squares
4. Leave one 10 X 10 cm square of 100% white cotton
fabric out from getting stained
5. Label the squares
a. A.1-A.12
b. H.1-H.12
c. T.1-T.12
d. W.1-W.12
e. White
control (no stain)
6. Prepare stain, mix well for five minutes:
a. 100 ml. of
ketchup
b. 100 ml. of mustard
c. 100 ml. of purple grape juice
d. 100 ml. of ravioli sauce
e. 100 ml. of chocolate syrup
f. 100 ml. of black coffee
7. Stain the 48 10 cm X 10 cm squares
a. Let fabric
soak for two days (wait for 48 hours before performing the next step)
b. Let the stained fabric dry after taking out of the
bowl
8. Set the Washing machine to Permanent Press with
cold water wash
9. Wash cotton squares as followed:
a. T.1-T.12
with 100 ml. of Tide
b. A.1-A.12 with 100 ml. of All
c. H.1-H.12 with 100 ml. of Arm and Hammer
d. W.1-W.12 with Water (no detergent at all)
10. When cycle is done carefully place in the drying
machine (keep the drying machine on the same cycle as the washing
machine)
11. Repeat step #8 and #9 with a different detergent
for other three groups
12. After all washing and drying is done take the
material to Tree Top’s Colorimeter.
13. Carefully measure the “L” level of each piece of
fabric under the Colorimeter
14. Record results.
RESULTS
The original purpose of this experiment was to compare the
effectiveness of different brands of detergent in removing stains from
cotton cloth.
The results of the experiment were that Tide’s “L” value was 81.49,
Water Control’s “L” value was 79.40, All’s “L” value was 78.33, and Arm
and Hammer’s “L” value was 78.98. Tide with 81.49 was clearly the
best.
See the table and graph below.
My hypothesis was that Tide would remove the test stains most
effectively.
My hypothesis should be accepted, Tide worked the best as shown by the
Colorimeter.
After thinking about the results of this experiment, I wonder if any if
the affect results:
• Different type of cloth (silk, linen, and wool)
• Washing temperature (cold vs. warm)
• Amount of detergent used (would 1/2 work as well)
If I were to conduct this project again I would use more cloth
samples. I would only use one stain at a time. One group
would be stained with only one thing and be washed with one specific
detergent.
I would test more detergents, including Tide, All, Cheer, Arm and
Hammer, and Kirkland Signature detergent.
I would use the stains: butter, ketchup, mustard, purple grape juice,
and black coffee. I wouldn’t do the ravioli sauce and the
chocolate sauce because they aren’t really things you eat on an
everyday basis.
I would also have one more control group, a stained cloth with no
washing to show how much the stain had actually been removed.
Introduction
Cleanliness is an important factor in human health and comfort.
Many people stain their clothes and don’t know the best way to take the
stain out. It would be a good idea to find out what type of
detergent is the most effective on stains.
Textile Materials
Textile originally meant a woven fabric, but almost all fabrics today
are considered textile materials. Textile mills can produce
huge rolls of all sorts of fabrics like cotton, wool, nylon, and many
others. The material comes from plants such as, cotton, flax,
hemp, jute, and ramie. The fiber from these help produce textile
materials.
Cotton
Fiber from the seed pod of the cotton plant, was used in India and
South Africa before 2,000 B.C. The cotton bush is a tropical or
subtropical bush/shrub producing soft white pods with downy fibers and
oil-rich seeds. The fiber is spun into thread and used to make a
soft, breathable textile. Cotton is a valuable crop because only
about 10% of the raw weight is lost in processing. In addition to
the textile industries, cotton is used in fishnets, coffee filters,
tents, and bookbinding.
Flax
The flax plant produces the bast of the fiber used to make linen,
yarn, and cloth. It originated in the Mediterranian region by
Swiss Lake Dwellers, around 8,000 B.C.
Silk
Silk is a continuous protein filament secreted by silkworm larvae in
order to make their cocoons. The species Bombyx mori is the
variety most commonly cultivated, as it produces especially fine,
lustrous, white fibers. Silk was developed in China c. 2700 B.C.
Washing Machines and
Washing Clothes
Washing machines are automatic and motor powered. The most common
washing machine is called the Agitator Washing Machine.
About 100 years ago they didn’t use washing machines, instead people
used washboards. Usually washboards are make out of tin and
glass. They also had to use two washtubs, one would have warm
soapy water and the second one would have clean water inside. The
soapy water tub would be the one to wash the clothes and the clean
water tub would be the one to rinse the clothes. The soap in the
tub would usually be made of melted pig’s fat and lye. Most rich
families would buy perfume to add with the soap so their clothes also
smelled good.
Stain
A stain is a dirty or discolored area on clothes caused by oil, grease,
dirt, food, or dye. Several stains were used in this project:
• Ketchup-red is usually made out of tomatoes.
• Mustard-yellow and is made out of powdered mustard
seeds.
• Black coffee-black and made out of water and ground
coffee beans.
• Purple Grape Juice-purple and made out of purple
grapes
• Chocolate syrup-brown and made out of melted
chocolate and other sugars.
• Ravioili Sauce-red and made of tomatoes and parsley.
Boosters
Boosters advance the soil and stain removal, brightening, buffering,
and water softening of detergents.
Bluing
Bluing is blue dye taken up by fabrics in the wash or rinse.
Bluing absorbs the yellow in the light spectrum interacting with the
yellow of many fabrics.
Bleaches
Bleaches whiten and brighten whites and help remove stubborn
stains. They convert soils to colorless stains and then wash them
away. Liquid chlorine bleach can also disinfect fabrics.
Oxygen bleach is gentler and works safely on most washable materials.
Enzyme
Enzyme pre-soakers are used for soaking items before washing to remove
stains and soils. When they are added to wash water it increases
cleaning power.
Fabric Softener
Fabric softeners added to the final rinse or dryer make fabrics softer,
fluffier, and decrease static cling, wrinkling, and drying. They
also make ironing easier.
Soap
Soap is a solid, liquid or powdered preparation that is made by
potassium or sodium hydroxide reacting with animal or vegetable
oils. Soaps are usually used with water and may contain
scents/perfumes and other additional ingredients.
Detergent
Detergents are put on materials to help remove dirt and other
stains. The ingredients in detergents are usually called
surfacants, and they are made up of big molecuels. When
detergents were first made they weren’t soluble and
biodegratable. Liquid detergents disolve easily. Solvents
are the part of detergent that does the dissolving and solute is the
one that dissolves.
Liquid detergent is most commonly used in washing machines.
Detergent that is factory made has different chemical makeup than
soap. A detergent molecule will have one end cling to the dirt or
stain while the other end will cling to the water.
Hunter Reflectance Spectrophotometer (Colorimeter)
A colorimeter is a special machine that identifies/measures the color
of an object such as 100% white cotton material. The Colorimeter
uses scales L, A, and B values to measure the whiteness and darkness of
an object. The ‘A’ values measure green (negative values), and
redness (positive values). The ‘B’ values measure blueness
(negative values), and yellowness (positive values). The ‘L’
values measure the lightness and darkness of an object (0 is black and
100 is white).
Summary
Cleanliness is an important factor in human health and comfort.
Many people stain their clothes and don’t know the best way to take the
stain out. It would be a good idea to find out what type of
detergent is the most effective on stains.
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“Colorimeter” World Book Encyclopedia, 2001
“Detergents Washday Winners.” Consumer Reports August 2003
"Detergents," World Book Encyclopedia, 2004.
Graf, Sue, Personal interview. December 15, 2005.
“Laundry Detergents Washday Winners.” Consumer Reports October 2005
Nevue, Carrie Jo, “The Effect of Different Detergents on the Removal of
Stains” http://www.selah.k12.wa.us/SOAR/SciProj2003/CarrieN.html
November 9, 2005
“Products and Ingredients,”
http://www.sdahq.org/sdalatest/htm/soapproducts1.htm
“Textile Materials and Technologies.” Cotton, flax, and Silk,
http://char.txa.cornell.edu/media/textile/textile.htm 1/18/06
“Which Detergents Clean Without Cleaning Out Your Wallet?” Consumer
Reports August 2004
Wilson, Kierstin. “Which Laundry Detergent is Most Effective in
Removing Stain?”
http://www.selah.k12.wa.us/SOAR/SciProj2003/KierstinW.html November 9,
2005.
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ACKNOWLEDGEMENTS
I would like to thank the following people for helping make my project
possible:
• My parents for helping me purchase the materials
for this project and for helping me along the way and as needed.
• All of my classmates at S.O.A.R. for helping me
find the information I needed.
• Mr. Newkirk for helping me with my project and my
report and helping me with all of my formatting along the way.
• Mrs. Viernes for helping me with my formatting,
report and spelling/grammar. I would also like to thank her for
helping me with my graphs.
• Sue Graf for helping me use the Colorimeter at the
Tree Top Technical Lab. She helped me use and record my results
from the Colorimeter.
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