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The Effect of Water Salinity and
Temperature on Oil Spreading Rate
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Researched by Lily-Anne
H.
2005-06
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PURPOSE
The first purpose of this experiment was to determine the rate at which
oil spread across the surface of water.
The second purpose of this experiment was to determine the effect of
temperature of the water on the rate at which oil spread across the
surface of water.
The third purpose of this experiment was to determine the effect of
salinity level of the water on the rate at which oil spread across the
surface of water.
I became interested in this idea because I had heard news reports about
oil spills and saw images of volunteers who had cleaned birds covered
in a tar-like substance. I was instantly concerned and decided I
would take this opportunity to see how quickly responders must be at
the spill site to effectively contain the oil and prevent such
incidents.
The information gained from this experiment could help those
responders, whether local volunteers or government agencies, to contain
oil and recover it. Also citizens who live near bodies of water
may be able to use this information to contain local spills on their
own property or nearby bodies of water.
HYPOTHESIS
My first hypothesis was that the oil would spread at least 0.05
centimeters in radius per second.
I based my first hypothesis on an article found at
gpa.unep.org/facts/fate.htm. The Global Marine Oil pollution
Information Gataway states, “Only ten minutes after a spill of 1 ton of
oil, the oil can disperse over a radius of 50 meters, forming a slick
10 millimeters thick.” That is approximately a 0.42 cm radius increase
per 16 ounces of oil spilled per second. When 50ml is used that
would be about a 0.05 cm radius increase per second.
My second hypothesis was that the colder the temperature the slower the
oil would spread across water.
I based my second hypothesis on an email from Stephanie Grenon, a
member of ITOPF; a company that plays a great part in the cleaning and
preventing of oil spills. She stated, “Generally, the viscosity
of oil will be influenced by the ambient temperature (if it is warm, it
will be less viscous so it will spread more rapidly).”
My third hypothesis was that salinity would not affect the rate at
which oil spreads across water.
I based my third hypothesis on another email from Stephanie
Grenon. She stated, “Salinity of the water will not have any
influence on the spreading of oil.”
EXPERIMENT DESIGN
The constants in this study were:
• Amount of oil used (50ml per trial)
• Size of container (56cm x 41cm x 13 cm)
• Shape of Container (rectangular)
• Amount of water used (14 liters when indicated)
• Number of repeated trials (3)
• Type of water (well water)
• Type of salt used
• Temperature of standard (21° Celsius)
• Type of Oil (Heavy Duty Straight 30 weight Pennzoil
Motor Oil)
• Size of plexiglass ( at least 50cm x 80cm)
• Rate at which the oil is spilled into water
• Plexiglass height above water (7 cm)
• Syringe height above water (1 cm)
• Height of camera (90cm from ground)
The manipulated variables were the temperature of water and salinity
level in water.
The responding variable was the oil-spreading rate.
To measure the responding variable, I took a plexiglass grid and put it
across the top of my container. I began a video camera and “spilled”
the oil by using a syringe placed through a hole in the center of the
plexiglass. I did this for all the experimental trials of each
experimental group. After reviewing the video in slow motion I
would record the elapsed time and the two “diameters”; north to south
and east to west. Using this I found the rate by taking the
average “diameter” of slick divided by the seconds elapsed.
MATERIALS
| Quantity |
Item Description |
| 1 |
Container (56cm x 41cm x
13cm) |
84 liters total
|
Water (14 liters when
indicated) |
1
|
syringe |
1
|
video camera with timer |
1
|
tripod |
| 1 |
thermometer |
| 1 50cm x 80cm |
Plexiglass sheet |
1
|
Ruler |
1
|
Meter stick |
| 6 sheets |
Polypropylene Pads (Cut
into fourths) |
1
|
Triple Beam Balance |
| 490 grams |
Sodium Chloride (table
salt) |
PROCEDURES
I. Preparations
A. Fill one
container with 14 liters of water
B. Let container sit until at room temperature
(21° Celsius)
C. Place the plexiglass grid on top of the container.
D. Drill a hole in the center of the plexiglass that
is large enough for the nose of the syringe.
II. Spill the oil, Control Group
A. Using the
tripod place video camera directly above the spill and focused on the
spill zone. Begin recording. Verbally announce and record the
test group, test series and trial.
B. Fill syringe with 50ml of motor oil. Remove
the plunger. The syringe will allow for a steady rate of oil flow.
C. Wait until the oil has stopped spreading and stop
the video camera.
III. Dispose of Oil and Clean-up
A. Start by
recovering the oil with polypropylene pads
B. Take the pads and put them in a doubled up trash
bag.
IV. Use the same water for each of the three
trials. Dispose of the water afterwards. (When testing
brackish water just add the necessary salt for Ocean water, don’t dump
the water.)
V. Repeat parts I-III to complete 3 trials.
VI. Repeat steps I-V for more series of tests with a
temperature change. Make the following adjustments to the
original test:
A. Do a test at
11° C
i. From the tap
fill the tub again only with 11° C. (Tap water should go down
to 11° C, if not use icepacks or place outside in colder
weather. If below after brought inside and until 11° C.)
ii. Stir the water and place the thermometer in the
water. Wait until about 11° C
iii. Complete the test just as previously done in
steps II-V.
B. Do a test at
1° C
i. Fill the tub
with the coldest water available from tap. Take icepacks and lay
it in the tub. Place outside in colder weather overnight.
In cold conditions the water should go down to 1° C.
ii. Stir the icy water and place the thermometer in
the water. Wait until about 1° C
iii. Continue as in standard test parts II-V.
C. Set up a
test for 31° C
i. Fill the
container with 31° C tap water (which should be available).
VII. Repeat steps I-IV for a third series of tests
with a change in salinity. When doing the test make the following
adjustments
A. Do a test in
Brackish water (17.5 grams salt per liter of water)
i. After
preparing the water weigh a paper bowl (typical size is 8.5). Add
245 grams of salt to the bowl. Dump the bowl’s contents into the
water for brackish water.
ii. Stir the water to dissolve salt
iii. Continue as in standard test, steps I-II.
B. Do a test in
Ocean water (35 grams salt per liter of water)
i. After
preparing the water use the bowl described in section ‘B’ and add
another 245 grams salt to the bowl. Dump into water. This
gives the total 490 grams of salt in the tub for ocean water.
ii. Stir the water to dissolve salt
iii. Continue as with standard test.
VIII. Draw a conclusion and find your average results
for each test. Compare the standard with the variables tested.
A. Once all 18
individual tests (be sure you complete 3 trials for each group) are
complete, review the video.
i. When the oil
first touches the water surface write down the time on the recorder,
minutes, seconds and frames (1/30ths of a second).
ii. When the oil reaches the determined point also be
sure to record the time.
iii. Find the difference and enter it into the data
table.
iv. Round the distance oil spreads north-south and
east-west.
v. Average the spread distances
vi. Find the rate per second and enter it into the
data table.
vii. Create graphs to represent the data.
IX. Dispose of all contaminated materials.
A. Take all
materials that have been contaminated (syringe, plexiglass, tub,
polypropylene pads, etc.) to a facility where they will be cleaned and
gotten rid of.
RESULTS
The first original purpose of this experiment was to determine the rate
at which oil spread across the surface of water.
The second original purpose of this experiment was to determine the
effect of temperature of the water on the rate at which oil spread
across the surface of water.
The third original purpose of this experiment was to determine the
effect of salinity level of the water on the rate at which oil spread
across the surface of water.
The results of the experiment were that when 30 weight motor oil was
spilled onto fresh water it spread at an average rate of 0.19 cm/sec in
radius in 1 degree Celsius water. It also spread at an average
rate of 0.19 cm/sec in radius in 11 degree Celsius water. It spread at
an average rate of 0.16 cm/sec in radius in 21 degree Celsius
water. It spread at an average rate of 0.15 cm/sec in radius in
31 degree Celsius water. When 30 weight motor oil was spilled
onto brackish water at 21 degrees Celsius it spread at an average rate
of 0.20 cm/sec in radius. It spread at an average rate of 0.25
cm/sec in radius in ocean water at 21 degrees Celsius.
See the table and graph below.
CONCLUSION
My first hypothesis was that the oil would spread at least 0.05
centimeters in radius per second. The results indicate that this
hypothesis should be accepted, because the oil slick’s radius increased
from 0.15 cm/sec to 0.25 cm/sec in radius regardless of temperature and
salinity.
My second hypothesis was that the colder the temperature the slower the
oil would spread across water. The results indicate that this
hypothesis should be rejected, because the 1° water and 11°
water had faster spread rates than either the 21° water or the
31° water.
My third hypothesis was that salinity would not affect the rate at
which oil spreads across water. The results indicate that this
hypothesis should be rejected, because salinity did appear to have an
effect on the spreading. The fresh water (0 g/l) spill had a
spread rate slower than brackish water (17.5 g/l) which was slower than
ocean water (35 g/l).
After thinking about the results of this experiment, I wonder if
different viscosities of oil would affect spreading, in particular
would crude oil behave differently than refined oil such as the 30
weight used in this experiment. I also wonder if the amount of
oil spilled would affect spreading. It seems that the amount
spilled should somehow determine the maximum size of the slick, but
would it also affect the speed of spreading? I also wonder if the
temperature and salinity affect the final thickness of the oil slick.
If I were to conduct this project again, I would do more trials per
treatment. I would test more variations of temperature and
salinity. I would spill a larger volume of oil, maybe 200ml for
example. I would find a more effective way to know when the oil first
hit the water in each trial. I would also release the oil in a
more instantaneous manner.
Introduction
Oil or petroleum is a very valuable resource in today’s world.
Many people depend on it for everyday activities. Forty percent
of the world’s energy supply is from oil. Nearly 40% of that goes
to the US alone. Many today are worried we are going to run out
of this precious, black, tar-like substance that runs our cars and
businesses.
Oil is toxic. It is easily taken for granted because of its
everyday use but this material is deadly to the earth. Exhaust
from gasoline enters the air that surrounds us. Oil leakage can
seep onto concrete, into rainwater drains, or into the soil.
Finally some oil is even spilled at sea when being transported.
This spilling of oil is probably the one thing that can grab the
world’s attention. Tons of oil are spilled as tons are shipped
for our everyday uses.
The focus of this report is on oil spills, what happens during these
spills, along with how water can affect the results of a spill.
Part I: Oil
Spills
Background
Information
An oil spill is when oil or petroleum is released, usually into a
marine ocean environment, though it may also be in a body of fresh
water. This release can be intentional or unintentional, natural
or because of human action.
Oil
Composition
Oil is made from hydrocarbons. A hydrocarbon is when two
chemicals, carbon (C) and hydrogen (H) combine. Carbon
atoms combine in easily formed molecules shaped like rings, chains or
branches; the hydrogen atoms attach themselves to these molecules.
The hydrocarbons in petroleum can exit as gases, liquids or solids
depending on the temperature and pressure. Smaller molecules seem
to exit as gases. Gasses cam be found at the top of a petroleum
deposit or dissolved in a liquid. Hydrocarbons with five or more
molecules seem to be found in liquid form. Very large
hydrocarbons are seen as solids.
The number of molecules and form of oil determine the viscosity or
resistance to spread. The lower viscosity the faster the oil will
spread. A light crude oil for example will spread faster than
heavy crude that has the higher viscosity.
Along with hydrocarbons there are other “impurities” that are in an oil
compound. These could be sulfur or asphaltene for example.
Causes
of Spills
Once again oil spills can be natural or from human action.
Natural spills are from natural causes like leakage. Natural leakage is
when there is a geographic seepage in the ocean floor that allows the
oil stored underneath leak into the water columns above. Human
action cause spills because of the everyday use of oil in today’s
society. Our dependency means more oil is collected and more oil
is distributed in the world.
Human actions have a great hand in polluting the world’s waters with
oil. However, it is found that most of the oil spilled is
actually natural leakage or oil run off, very little is from tankers.
Oil run-off, although not considered an “oil spill,” still allows oil
into an ecosystem where harm can be done. This happens when
humans allow a car to leak oil onto pavement. This oil leaves a sheen
(rainbow effect) on the pavement and most of it seeps into drains that
flow into the ocean or bodies of fresh water. Oil run-off from
machinery at a farm or business also leaks into drains or into the
soil. The oil found in soil can then seep into our ground water
supply depending on the soil, oil type, distance to groundwater and
amount of rain. This is a rare situation, but it is still
possible.
Another main cause of oil spills is from tankers. This is
probably the most recognized type of spill. Because of society’s
need of oil, tankers are used to transport the oil. These tankers
can crash or the hull can be torn. This allows tons of oil
to freely enter the water column. A tanker spill can be from
machinery problems or human carelessness. Of all oil spills,
human error causes 46% and equipment failure is responsible for
34%. For every 1,000 tons of oil used 1 ton is emptied into the
ocean. Out of that one ton two-thirds of it are from everyday
things like a car leaking oil. Only one-third is an actual oil
spill. Another statistic shows that approximately 2.5 billion
pounds of oil is spilled annually.
Hazards
of Spills
From the Exxon Valdez spill it is now known that an oil spill can cause
much more damage than first anticipated. Effects on the marine
environment are notable even with less than 1 part per billion of oil
present. The lighter more volatile substances in oil such as
benzene are highly toxic to the marine environment but are easily
evaporated. Heavier components also play their part. Polynuclear
aromatic hydrocarbons (PAH’s) are less toxic but seem to do the
greatest damage because they last longer than the highly volatile
components.
Oil spills are very dangerous to marine wildlife. The main danger
of oil spills to animals is that the sticky oil may coat the
animal. Because of this birds’ feathers can be weighted
down. This can result in hypothermia, sinking and drowning or
becoming easy prey. Young seals can also suffer hypothermia or
drown. Also their scent can be disguised leaving them
orphaned.
Something else that can drastically affect animals is if they swallow
oil. This can cause ulcers or bleeding in the animal’s stomach.
Oil can damage a food chain by predators eating contaminated
prey. Animal’s airways or lungs become clogged from oil
too. A spill can interfere with breeding, and cause blindness or
eye problems, irritation or ulceration in skin, mouth or nasal
cavities, and red blood cell damage. Also oil can be
damaging to a whale’s baleen, or poison a young whale calf with its
mother’s milk. That is just a few of the many interconnected
problems that can occur during an oil spill.
Preventing
and Treating an Oil Spill
Today there have been changes to help prevent great damage when an oil
spill occurs. Government workers responsible for maintaining
control over oil spills have better training along with those who work
onboard tankers. New equipment is being developed. Some
equipment today is even supposed to predict how long it will be before
another big spill occurs in a certain area. Tankers are being
improved with double hulls and a more careful crew. However until
our dependency on oil ends there will still be oil spills.
Some of the materials used to clean, collect and contain oil spills are
listed below along with their purposes.
o Booms- Booms are floating barriers that contain an
oil spill. Booms have three main parts. The skirt is a
netting used to keep oil from slipping underneath the boom. There
is freeboard that rises above water to contain the oil and prevent
spilling over. A chain of cable is used to stabilize the boom.
o Skimmers- Are devices that float and basically skim
the water for oil that is stored in a compartment inside the
device. The skimmer blots oil with a sorbent and physically
separates the oil and water. These devices however become easily
clogged and do not last with a large spill or rough seas.
o Vacuums/Pumps- Specialized vacuums or pumps can
“suck up” oil and contaminated water to be cleaned. These are
usually used to keep oil off the beaches or to collect the oily water
that is collected on the beach itself.
o Releasing Chemicals- Chemicals can be released into
water to change how the oil behaves. Emulsion Breakers break down
emulsions so that the oil can be removed more easily from the
environment. Gelling agents can increase oil thickness and
decrease spreading. Herders are collecting agents.
Neutralizing agents react with the oil to create less harmful
liquids. Sinking agents let the oil sink. Viscoelastic
Additives include solidifying gelling agents that convert oil and makes
it easier for the oil to be collected in nets but this process takes
too much time.
o Sorbents- Sorbents are used to absorb the oil for
disposal. Sorbents can be chemicals or a material object such as
polypropylene. Also sorbents are lightweight, inexpensive but sometimes
can sink when heavy with oil. Polypropylene pads are layed over
an oil slick and the material soaks up the oil into its fibers.
These pads can be collected and properly disposed of.
o Burning- The burning of oil allows for 98% of the
oil spill to burn away. This “in-situ” burning however is also a
threat to the environment. The smoke and gasses released from a
fire could be a threat, though it is unproven what effect burning has
on an ocean environment or its extent of damage.
o Dispersants- Dispersants are to help the oil during
its spreading. Dispersants are chemicals sprayed over the spill
by aircraft and break up the compounds in oil.
o Bioremediation- Bioremediation occurs when
organisms eat oil naturally. These organisms digest the oil they
can and get rid of it as waste. This process is slow and is sped up by
adding nutrients. The waste also contains minerals. The minerals
left in the water column increases algae growth. As the algae die
they lower the oxygen rates of the water. This creates even more
harm to the environment.
Part
II: Oil on Water
Spreading
or Distribution
The instant oil hits a surface it begins to spread or distribute
itself. Gravity, surface tension, wind, waves, currents and oil
viscosity affect distribution or spreading. It is said that in 10
minutes after a 1-ton spill, the spill’s radius will be over 50 meters
with a thickness of about 1 millimeter. The conditions of such a
spill are not provided, just the fact that oil can spread rather
quickly over water’s surface. Gradually the oil’s compounds will
break up or the oil will separate into small droplets and disperse into
the water column. The large droplets will rise and sink again as
smaller droplets. Eventually there is another slick made
from small oil droplets that rise.
Dissolution
Dissolution is when oil dissolves into the water. As oil spreads,
the water- soluble substances dissolve into the water and the oil
spreading begins to slow down as more of the oil’s components are lost.
Emulsions
and Oxidation
Oxidation and Emulsion occur when oil mixes with another
substance. Theses two forms of weathered oil are actually very
similar.
Emulsions happen when oil and water mixes. The strongest are
30%-80% water. The remaining material is oil. Emulsions are
often referred to as “chocolate mousse.” Oxidation is a chemical
reaction between oil and oxygen. This can create a tar ball for
example.
Biodegradation
Biodegradation is when organisms eat the oil, and take nutrients from
it and dispose of it as waste. This gets rid of the oil but
leaves items that don’t digest at the sea floor.
Evaporation
Many of oil’s lighter compounds evaporate. Some of these
compounds could be petrol, kerosene and diesel. These compounds
start to evaporate within 25 hours.
Sedimentation
and Weathering
Sedimentation or sinking occurs when the oil has a density of more than
one in fresh or brackish water. This includes crude oils.
However sea water density is 1.025. Only very few heavy crudes
can sink in these conditions unless weathering has occurred. Also
if oil is burned some residue is heavy enough to sink. When the
oil has been on the water’s surface after a time it tends to thicken or
weather. Weathered oil can be emulsions or oxidized tar balls for
example.
Part
III: Water
Surface
Tension
“In physics, surface tension is an effect within the surface
layer of a liquid that causes the layer to behave as an elastic
sheet.” From “Wikipedia” located at:
<http://en.wikipedia.org/wiki/Surface_Tension>.
Surface tension is, as described above, when the surface of a liquid,
specifically water, is forced to behave as a “sticky” substance.
This is caused by the attraction between the molecules found in a
liquid. These molecules are pulled equally in all directions by
the other liquid molecules. This leaves a net force of
zero. Molecules at the surface are pulled in by the molecules
deeper within the liquid. As there are not any liquid molecules
outside the surface there is nothing to balance out this pull. So
the surface molecules now have to be balanced by the resistance of the
liquid to be subject to the inward pull. There may also be a
small outward attraction from the air molecules. The air is much
less dense however and does not have a major effect.
Temperature
To define temperature “heat” must be understood. Heat and
temperature are not the same thing. Heat is specifically the
internal energy of an object. All the atoms or molecules of an object
move. Internal energy is how much energy these particles contain
as they move. The more violently the particles move, the more
energy. This energy determines how hot or cold something
is. Temperature is the measurement used to define the amount of
energy or heat of an object.
Salinity
Salt is scientifically called sodium chloride. Salt though in
reality is an ionic compound full of positively charged cations and
negatively charged anions. The product is therefor neutral.
Solutions of salt in water are electrolytes. These electrolytes
can conduct electricity.
Salinity is generally defined as the salt content of bodies of
water. Fresh water such as rivers, lakes, and streams have less
than 0.05% salt. Anything over that is called brackish water
until ocean water. Ocean water is approximately 3.5% salt (35
grams of salt per liter of water)
Salinity is measured in Practical Saline Unites or psu. Psu
determines the conductivity ratio of sea water to a KCl (K=potassium,
Cl=chloride) solution. The ratio has no unit, so 35 psu is equal
to 35 grams per liter.
Summary
Overall oil spills are a major threat to the environment because it is
so toxic. Thus people need to be careful about their use of
oil. Oil can be spilled by run-off, leakage or tanker
spills. The more oil is used, the more likely a large spill will
occur.
Oil is made of hydrocarbons. Along with these hydrocarbons there
are impurities in the oil. Oil is refined at factories in order
to get rid of these impurities for everyday use. Oil collected
from reservoirs is called crude. These have more impurities and
are less able to spread out. This is how viscous the oil is.
Spilled oil can be recovered or disposed of by booms, skimmers,
sorbents, pumps, chemicals, in-situ burning, dispersants or by
bioremediation. Once on water oil will spread or distribute
itself on the surface, dissolve (some of the components), emulsify,
oxidize, degrade by organisms, evaporate, settle, or weather.
Surface tension is when a liquid behaves like an “elastic sheet.”
This is caused by an improper balance between inward and outward
forces. Salinity is the amount of salt dissolved into
water. Temperature is the measurement of heat.
Considering the amount of oil used by societies world-wide, it is
extremely important to avoid oil spills. Since some spills will
occur anyway it is critical to know how spills spread and how to best
recover the oil.
|
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2002.
“Behavior of Oil Which Has Been Spilled at Sea.” Behavior of Oil.
November 9, 2005
<http://www.oil-spill-web.com/handbook/1.htm#oil%20which%20has%20been%20spilled%20at%20sea>.
Catania, Peter J. “Energy Supply.” World Book Online Reference Center.
2005. World Book, Inc. 12 Oct. 2005
<http://www.worldbookonline.com/wb/Article?id=ar181250>.
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2005. World Book, Inc. 12 Oct. 2005
<http://www.worldbookonline.com/wb/Article?id=ar182428>.
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<http://www.worldbookonline.com/wb/Article?id=ar425600>.
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<http://www.ndt-ed.org/GeneralResources/Units/ConversionChart.htm>.
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October 26, 2005 <http://www.itopf.com/fate.html>.
Gordon, Arnold L. "Ocean," World
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"Oil," World Book
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<http://www.ucs.lousiana.edu/~hxk6110/PageThree.html>.
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Response. August 16, 2005
<http://response.restoration.noaa.gov/topics_subtopic_entry.php?RECORD_KEY%28entry_subtopic_topic%20=entry_id,subtopic_id,topic_id&entry_id(entry_subtopic_topic)=184&subtopic_id(entry_subtopic_topic)=8&topic_id(entry_subtopic_topic)=1>.
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Patin, Stanslav. “Environmental Impact of the Offshore Oil and
Gas Industry.” October 26, 2005
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“Salinity” Wikipedia.
January 25, 2006. <http://en.wikipedia.org/wiki/Salinity>.
“Salt” Wikipedia.
January 25, 2006. <http://en.wikipedia.org/wiki/Salt>.
“Sea Water” Wikipedia.
January 25, 2006. <http://en.wikipedia.org/wiki/Sea_water>.
“Surface Tension” Wikipedia.
January 18, 2006. <http://en.wikipedia.org/wiki/Surface_Tension>.
“The Effects of Oil on Wildlife” Marine Environment Protection.
January 13, 2006
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“US EPA.” Response
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<http://ww.epa.gov/oilspill/oiltech.htm>.
“What Happens to Oil in Water?” Global Marine Oil Pollution
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<http://www.gpa.unep.og/facts/fate.html>.
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ACKNOWLEDGEMENTS
I would like to thank the following people for helping make my project
possible:
• My parents for allowing me to experiment in oil in
their precious kitchen.
• Mr. Newkirk for correcting rough drafts and setting
an expectation to meet.
• Professor Yapa Poojitha for allowing me to call and
ask for advice.
• Will Strand from the Department of Ecology for
donating polypropylene pads.
• Stephane Grenon, Chris Coffin, Will Strand, Eric
Williams, Yapa Poojitha, Mark Dirx, Paul Meyers, Matthew Quinney, and
Norman Hepner for generous emails full of advice.
• My regular teachers for allowing small exceptions
when extra time on the project was needed.
• My peers for their advice and support.
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