Burn Time of Various Rechargeable Batteries in Extreme Cold

Researched by Tayler T
2003-04



PURPOSE

The purpose of this experiment was to determine which brand of secondary batteries has the longest electrical burn time in extreme temperatures, (like those of Mars). 

I became interested in this idea because I am a skier and am aware that some skiing resorts have remote sensors on top of the mountain and wonder how the batteries cope with that. 

The information gained from this experiment could help mountain climbers, construction workers, people who live in the Arctic, or any one who lives in unusually cold climate to know what brand of secondary batteries to buy for any of their battery required appliances such as flashlight, toys, electronics, etc.


HYPOTHESIS

My hypothesis was that Duracell would have the longest electrical burn time in extreme temperatures.

I based my hypothesis on a past study by Rachael Lessard, a 7th grade researcher, who said that Duracell puts out the most voltage the longest in extremely cold temperatures. 


EXPERIMENT DESIGN

The constants in this study were:
* The chemistry of the battery
* Voltage of batteries
* Time each battery was charged
* Charger 
* Devise used to drain the batteries
* Same batteries for each trial

The manipulated variable was the extreme temperature.

The responding variable was the battery’s output.

To measure the responding variable I timed the life of the battery using an electronic clock.


MATERIALS


QUANTITY  ITEM DESCRIPTION
5lbs Dry ice
Ziploc bags
1 pair  Gloves
1 pair  Eye Goggles
 AA secondary Sanyo battery
AA secondary Ray-o-Vac battery 
AA secondary Duracell battery
Clock 
ice chest
Light bulbs
Copper wires
alligator clips
Battery Charger
AA battery holder


PROCEDURES

1. Put on Safety Equipment
2. Label three Ziploc bags for each brand of batteries
3. Put four of each brand of battery into the Ziploc bag with their brand name on it
4. Label three more with each brand and then write “done”
5. Place four Duracell batteries into the battery charger
6. Plug the charger into a wall outlet 
7. Charge Duracell batteries for 1hour 
8. After the batteries are finished charging, place them into the plastic bag with the word “Duracell” and “Done” on it
9.Repeat steps3-9 with the remaining 2 brands of batteries
10.Place 5pounds of dry ice into the ice chest
11. Place one Duracell battery into the battery holder.
12.Set the clock to 12:00
13.Hook the alligator clips onto the clock
14.Place the battery, (which is in the battery holder) into the ice chest and onto the dry ice
15.Place lid onto the ice chest but do not put it on tight
16.Wait for the light bulbs to go out and the clock to stop 
17.Record the time on the clock
18. Unhook the alligator clips from the clock
19. Repeat steps 13-20 for the remaining brands of batteries and three more trials
20. Compare results


RESULTS

The original purpose of this experiment was to determine which brand of secondary batteries has the longest electrical burn time in extreme temperatures, (like those of Mars). 

The results of the experiment were that Sanyo had the longest burn time in dry ice with an average of 37 minutes.  Ray-o-Vac came in second with an average of 21 minutes. Duracell came in last with an average burn time of only 12.5 minutes. 

Sanyo also came in first in room temperature with an average burn time of 247 minutes. Ray-o-Vac came in second with an average burn time of 245 minutes. Duracell came in last again with a burn time average in room temperature of only 210 minutes.

See the table and graph below.


CONCLUSION

My hypothesis was that Duracell would have the longest burn time in extreme temperatures.

The results indicate that this hypothesis should be rejected because Sanyo had the longest electrical burn time.

Because of the results of this experiment, I wonder if the batteries would perform similarly at even colder temperatures, like liquid nitrogen. I also wonder how the batteries would operate in really warm temperatures. Another thing I wonder is how secondary nickel cadmium or alkaline batteries would perform. The last thing that I wonder is how primary batteries would work in these temperatures. 

If I were to conduct this project again I would conduct more trials. I also would use a wider variety of batteries. Another thing I would change would be to compare the chemistry type of the battery.


RESEARCH REPORT

Introduction
There are two different kinds of batteries, a primary battery and a secondary battery. A primary battery is a disposable battery. When one or more of its chemicals are gone, it is no longer good. A secondary battery is also known as a rechargeable battery. Unlike the primary battery, when one or more of its chemicals are gone, it can be recharged so it’s chemical can be restored. A secondary battery can be charged, and discharged as many times as needed. 
Dry ice is made up of frozen carbon dioxide. Carbon dioxide is a gas, which we exhale when we breathe.

Nickel Metal Hydride Batteries
A Nickel Metal Hydride, (NiMH) battery has no memory like other batteries. However, The NiMH batteries are able to store up to 70%more than Nickel Cadmium batteries because they contain no cadmium. Even though the NiMH battery can store up to 70% more then a common NiCd. The metal hydrogen link is usually very weak and a lot of hydrides stay in the metallic stage. Today, many Nickel Metal Hydride batteries are replacing Nickel Cadmium batteries.

Dry Ice
Dry ice is made of frozen carbon dioxide. Carbon dioxide is a gas, which we exhale when we breathe. Dry ice got its name when it was discovered that it could go from a solid to a gas without going to a wet liquid phase. Carbon dioxide is also a gas which plants use during photosynthesis. The gas carbon dioxide is also the carbonation in liquid that makes it soda. Dry ice is commonly used for freezing things because of its cold temperature: with negative 78.5ºC, (-109.3ºF). Dry ice can also be used for air travel, beverages, pools and Jacuzzis, baking industries, boating, branding cattle and horses, carbonating liquids, and special effects.

Electricity
 Electricity is one of the most important forms of energy. Electricity is the flow of electric charge. You cannot touch, hear, smell, taste, or see electricity. We only know it’s there because of what it does. Electricity has many forms. It creates, light, heat, and offers energy to household electrical devices. Just about all of the world’s electricity is produced by power plants. Even nature carries electricity. For example lightning is just a big surge of electricity.
 Certain rocks or stones containing amber are electrically charged when rubbed with cloth. There are also certain sea creatures that give out electric shock when touched by other things. Some example of these sea creatures are electric eels and jelly fish. Electricity is a very efficient source of energy if handled with caution. If there are faulty wires or an overloaded socket, the energy will build up and may cause a fire. Even a low voltage electric current can kill you if you touch it with wet hands or even if your standing on something wet. 

Electrodes
Electrodes are components of an electric circuit that connect the ordinary wiring of the circuit to a conducting medium like an electrolyte. The positive electrode is called the cathode. The negative electrode is known as the anode. The standard dry cell battery supplies carbon anode and a zinc cathode in coalition with an electrolyte mix.

Secondary Batteries
A secondary battery is also known as a rechargeable battery. In a rechargeable battery the energy is fed by an outer source, which is then stored inside the battery. This energy is stored inside as chemical energy. Unlike primary batteries, rechargeable batteries have chemical reactions that go one way while charging and the opposite way while discharging. A rechargeable battery can be charged and discharged as many times as needed. Modern rechargeable batteries are made up of zinc-chlorine, sodium, sulfur, nickel metal hydride, and lithium-iron. The most commonly used rechargeable battery types today are alkaline, nickel cadmium, and nickel iron.

Electric Current
A current is a flow of electricity. The electric current is transported by electrons, which circle the nuclei of atoms. Each individual electron is able to carry a very small amount of electric charge. When a flow of electrons move from atom to atom the stream of the charge the atoms carry is called electric current. An example of electric current in action is when batteries produce light, sounds, etc. in appliances. 

Atoms and Ions
Atoms are electrically neutral: the number of electrons that have negative charge are equal to the number of protons in the nucleus, which holds the positive charge. When an atom gains or loses one or more electrons then the electrons and protons do not equal the same number. This is called an ion. An atom, which loses an electron, forms a positively charged ion since there are more protons then electrons. When this occurs the ion is called a cation. An atom which gains one or more electrons then is negatively charged because there are now more electrons then protons. This is called an anion. 

Batteries
A battery is a device which produces electricity by chemical action. A battery consists of one or more electric cells. Each cell has chemicals to produce electric current. The word “battery” means a group of connected cells. This term is usually used to refer to single cell batteries such as those used in flashlights or toys. Batteries serve as a convenient source of electricity. There is a wide variety of batteries. They are classified by their basic design. A battery can also be classified by their general type of electrolyte. The design depends on the batteries electric output. Primary batteries must be disposed of after one or more of their chemicals are gone. Rechargeable batteries can be recharged after they are discharged. 

Thermodynamics
Thermodynamics is the study of the laws that govern the conversion of energy from one form to another, the direction in which heat will flow, and the availability to do work. Thermodynamics exists in many forms such as heat, light, electrical energy, and chemical energy. The first law of thermodynamics is that energy may change from one form to another, but may not be created or destroyed. The amount of energy and/or matter in the universe stays the same, but changes from one form to another. The second law of thermodynamics says energy will flow from high-energy areas to toward lower energy areas, so heat flows from hotter things to cooler things. 

Electrolytes
An electrolyte is a very important part of the battery. The ions would not be able to travel if it wasn’t for the electrolyte. This means that there would be no electric current. An equal number of positive and negative ions are released when as electrolyte dissolves. Electrolysis happens when there is a reaction between an electrolyte and electrode.

Watts
Watts are a measure of electricity. Watts can be increased by current flow or voltage pressure. This measure of electric power was named after James Watt. To calculate watts you multiply amperes, (amps) by volts. Power companies charge customers by the amount of watts used per month. A Kilowatt is equal to 1,000 watts. Kilowatts are used when there is a large amount of watts. 

Insulators
Insulators are used to stop electric current from flowing into places where it would be dangerous. Dry wood, glass, mica, dry air, rubber and plastics are all insulators. An insulator conducts almost no electricity. Insulators are used to prevent electric current from flowing into an area. An insulator can also be called dielectrics. 

Electric Circuit
An electric circuit is the course followed by an electric current. In order for electricity to produce energy it needs to it must travel in an electric circuit. An electric circuit is made up of three main parts. The first one is a source of electric energy. The second thing is a device which uses energy. The third main thing that makes up electric circuit is a connection between the electric circuit and the device which uses energy. 

Summary
There are two different kinds of batteries, a primary battery and a secondary battery. A Primary battery is a disposable battery. When one or more of the chemicals is gone, it is no longer good. A secondary battery is also known as a rechargeable battery. Unlike the primary battery, when one or more of it’s chemicals are gone, it can be recharged so it’s chemical can be restored. A secondary battery can be charged, and discharged as many times as needed. 

The NiMH batteries are able to store up to 70%more then Nickel Cadmium batteries because they contain no cadmium. 

Dry ice is made of frozen carbon dioxide. The gas carbon dioxide is also the carbonation in liquid that makes it soda. Dry ice is commonly used for freezing things because of its cold temperature of ?78.5ºC, (-109.3ºF). 

Electricity is the flow of electric charge. You cannot touch, hear, smell, taste, or see electricity. Electrodes are components of an electric circuit. A secondary battery is also known as a rechargeable battery. In a rechargeable battery the energy is fed by an outer source which is then stored inside the battery. A current is a flow of electricity. The electric current is transported by electrons which circle the nuclei of atoms. 

The first law of thermodynamics is that energy may become different from one form to another, but may not be created or destroyed. The amount of energy and/or matter in the universe stays the same, but changes from one form to another. 

An equal number of positive and negative ions are released when an electrolyte reacts. Watts are a measure of electricity. Insulators are used to stop electric current from flowing into places where it would be dangerous. An electric circuit is the course followed by an electric current.

Bibliography

Knapp, Brian. “Nitrogen and phosphorus,” Grolier Education and Sherman Turnpike.U.S.1996.

Marshall, Brian. “What are amps, watts, volts, and ohms? ”December 3,2003
http://www.howstuffworks/.com/quest.onsol.htm

James, Stanley D. “Battery.” World Book Encyclopedia 1998

 “Dry Ice” January 15,2004
http://www.dryiceinfo.com

ACKNOWLEDGEMENTS

I would like to thank the following people for helping make my project possible:

  •  My family for taking me places and buying the materials.
  •  The employees at Cascade Fire & Safety Equipment.
  •  Mr. Newkirk for correcting all my papers.
  •  Mrs. Helms for helping me on the computer.
  •  The employees at Artificial Ice & Fuel Co.
  •  Katie and Christian for pushing me to try harder


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