Comparing the Effect of Electrical Load on a 
Fuel Cell and Rechargeable Batteries

Researched by Katie M. 
2003-04



PURPOSE

The purpose of phase one of this experiment was to measure the electrical output of a hydrogen fuel cell at different load levels.

The purpose of phase two was to measure the electrical output of both Nickel-Cadmium and Nickel-Metal Hydride rechargeable batteries at different load levels.

The purpose of phase three was to compare the electrical output of a hydrogen fuel cell with the rechargeable batteries at different load levels.

I originally became interested in this area last year when I was reading a newspaper article saying that auto manufacturers might start making cars operated by fuel cells. That lead me to conduct a study to see if the electrical output of a fuel cell changed when operated at different temperatures. Following that series of experiments I became interested in fuel cell output under low and high load levels.  At about the same time my brother was complaining about his rechargeable batteries not powering an electrical toy long enough. I decided to compare the fuel cell with rechargeable batteries.

The information gained from this experiment could help consumers decide which rechargeable battery to purchase. It could also help manufacturers decide whether a fuel cell would be preferable to rechargeable batteries for a given load.


HYPOTHESIS

My first hypothesis was that the fuel cell would produce more electrical output as the load decreases. I based this on Mrs. Theresa Koehler, an employee for Pacific Northwest Laboratories, who told me via e-mail that fuel cells produce more electricity at higher load levels.

My second hypothesis was that the rechargeable batteries would produce more electrical output as the load decreased. I based this on an email from Mrs. Theresa Koehler, who told me that batteries can respond faster than fuel cells.

My third hypothesis was that fuel cells would have an overall greater electrical output than the rechargeable batteries.  I based this also on a graph sent by Mrs. Koehler showing that fuel cells have a higher wattage per kilogram.

My fourth hypothesis was that the NI-MH rechargeable batteries would have an overall greater electrical output than NI-CAD rechargeable batteries.
I based this on a graph from Mrs. Koehler that showed this with wattage compared to kilowatt hours.


EXPERIMENT DESIGN

The constants in this study were:
* The test group size
* The batteries
* The fuel cell
* device to recharge the batteries and the fuel cell
* The room that the experiment takes place 
* The temperature that the experiment is conducted 
* The type of battery
* The type of fuel cell
* The type of fuel used in the fuel cell

The first manipulated variable was the amount of electrical load that the fuel cell powered.

The second manipulated variable was the type of rechargeable battery.

The third manipulated variable was the amount of electrical load that the rechargeable batteries powered.

The responding variable was the electrical output of the fuel cell and the rechargeable batteries. 

To measure the responding variable I will use a computerized voltage probe made by Vernier Company and Logger Pro 3.0 software


MATERIALS
 
 

QUANTITY ITEM DESCRIPTION
1
 Hydrogen fuel cell
4
AA Nickel Cadmium batteries
4 AA Nickel Metal Hydride batteries
1
 probe 
1 room
2 1.5v light bulbs
1 computer
1 23 x 4 3/4in board 
1 Logger pro disk
light bulb holders
terminal strips
1 6 x 3 in stick of metal.
3  toggle switches
1 Knife Switch
1 battery holder
1 roll of split telephone wire.
1  solar panel
1 100 watt lamp
1 AA Ni-Cad and Ni-MH safe battery charger
8 Alligator clips


PROCEDURES

PREPARTION PHASE
1. Assemble the board
a. Screw the battery holder to one end of the board. 
b. Put two wire leads to the ends of the holder.
c. Screw the knife switch onto the board and then attach the leads to the switch.
d. Put two wire leads on the other end of the knife switch.
e. Attach a Thamas Komos multimeter (set to 200ma) to one lead.
f. Attach the terminal strips to the board opposite of each other.
g. Attach the other metal probe on the multimeter to one of the terminal strips.
h. Attach the light bulb holders in a row at the end of the board.
i.  Put the correct light bulbs into the holders. 
j. Put 4 pieces of wire onto both terminal strips.
k. Attach alligator clips on to all 8 pieces of wire.
2. Set up the logger pro and Vernier volt probe
a. Install Logger Pro 3 into a strong computer.
b. Set the time to 2 hours and record 60 times an hour
c. Put in the desired battery and number of light bulbs. 
d. Attach the probe to the computer and to channel 1. 

 I. Phase 1: Fuel Cell
1. Get the fuel cell ready.
a. Take off the protector tubes on the side.
b. Use the syringe to pump water through the side of the cell.
c. Stop when you put one ml of water into the cell. 
d. Put 47 ml of water into the container that holds the gas containers. Shine a lamp straight onto the middle of the solar panel, with the panel flat, to break the water a part until the gas containers have gas bubbles coming out of the top. 
2. Do test one with load of 1 small flash light bulb
a. Start the collecting. Use a multimeter to measure the amperage.
b. Conduct trial two. Use the same directions above (1a - 1d and 2a)
c. Conduct trial three. Repeat step 2b.
d. Conduct trial four. Repeat step 2b.
3. Do test with load of 2 small flashlight bulbs
a. Repeat steps 1a-2c.

 II. Phase 2: NI-CAD
1. Do test one with 1 flash light bulb
a. Start the stopwatch. Use a multimeter to measure the output of the cell every minute. Stop when the battery runs out of energy.
b. Conduct another trial. Use the same directions above.
c. Charge the battery for seven hours. 
d. Conduct the final two trials of this load.
2. Do test two with 2 flash light bulb
a. Repeat steps 1a-1d.

 III. Phase 3: Ni-HM
1. Do test one with 1 flash light bulb
a. Start the stopwatch. Use a multimeter to measure the amperage
b. Conduct another trial. Use the same directions above 
c. Charge the battery for seven hours.
d. Conduct another trial. Use the same directions above 
e. Conduct another trial. Use the same directions above 
2. Do test two with 2 flashlight bulb
a. Repeat steps 2a-2e.


RESULTS

The purpose of phase one of this experiment was to measure the electrical output of a hydrogen fuel cell at different load levels.

The purpose of phase two was to measure the electrical output of both Nickel-Cadmium and Nickel-Metal Hydride rechargeable batteries at different load levels.

The purpose of phase three was to compare the electrical output of a hydrogen fuel cell with the rechargeable batteries at different load levels.

The results of the experiment were that the Ni-HM batteries performed the best. They held an almost constant voltage throughout the 2 hour test. The fuel cell did the worst staying at about zero for the majority of the two hours. All of the batteries and the fuel cell did the best at lower load levels

See the table and graphs below


CONCLUSION

My hypothesis was that the fuel cell would produce more electrical output as the load decreases. The results indicate that this hypothesis should be accepted.

My second hypothesis was that the rechargeable batteries produce more electrical output as the load decreased. The results indicate that this hypothesis should be accepted.

My third hypothesis was that fuel cells would have an overall greater electrical output than the rechargeable batteries. The results indicate that this hypothesis should be rejected.

My fourth hypothesis was that the NI-MH rechargeable batteries would have an overall greater electrical output than NI-CAD rechargeable batteries. The results indicate that this hypothesis should be accepted.

Because of the results of this experiment, I wonder if the fuel cell would perform the same if I used regular drinking water in the fuel cell instead of distilled water. I also wonder if the amount of time I charged the fuel cell and the batteries affect the experiment. I also wonder what would happen if I used different brands of batteries. I especially wonder if using a bigger fuel cell would have made the experiment a better comparison test.

If I were to conduct this project again I would conduct more trials. I might also try 2 more load levels. I could also record data for more than 2 hours. I might try 5 hours. I would also record data points less frequently so that my graphs would be easier to read. 



RESEARCH REPORT

Introduction
A fuel cell is a device that uses chemical energy to produce electricity. A rechargeable battery is a similar device, but does not store energy internally. There are both good and bad features about both of them. For example, batteries pollute while fuel cells are VERY expensive.

Fuel Cells
Comparing with Rechargeable Batteries
Rechargeable batteries and fuel cells are relatively similar in that the both operate with the same parts (electrolyte, anode and cathode) and they work on the same principle. They are different, though, in that batteries gather energy internally. 
Parts of a Fuel Cell
The main parts of a fuel cell are the electrolyte and the two electrodes. They are responsible for creating the electricity. 
Electrolyte
 The electrolyte is a liquid ionic conductor. It lies between the two electrodes. It is often made up of alkali metal hydroxide. The electrolyte carries the electrons and the ions to their respective electrodes.
Electrodes
There are two electrodes. The positive electrode is the anode. The negative electrode is called the cathode. The anode supplies the hydrogen and the cathode supplies the oxygen. The ions come from the cathode and move to the anode while the electrons start at the anode and travel to the cathode. 
History
The belief that fuel cells are extremely new technology is only partly true. They have been in the works for many many years; it is just that we have only lately begun to use them again. Here is a quick look at the history of fuel cells.

Allesandro Volta: (1745-1827) Volta was born in Como Italy. He came from a noble family. He was a physicist. He studied several science topics, but he is famous for inventing the first battery. The idea came from Galvani Lugi, who was dissecting a frog during a storm when the leg twitched. Volta redid that experiment to find out that the metal touching the frog caused the twitch. He researched this concept and later invented a wet cell battery called the Voltaic Pile. 

William Robert Grove: (1811-1896) Grove was a lawyer and then later a scientist. He developed a better wet cell battery in 1830; it was called the Grove Cell. The Grove Cell had platinum electrodes, half submerged in sulfuric acid and the other ends in separate containers of oxygen and hydrogen. The gasses from the sides combined to make an electric current and water. The concept of actually making water was very new back then so this was a very big deal. The new battery was named The Gas Battery. The Gas Battery was the first “fuel cell”.

Ludwig Mond: (1839-1909) Mond was a chemist who mostly worked on designing soda manufacturing and nickel refining. Along with his assistant, Carl Langer, Mond conducted several experiments with fuel cells. The fuel cells got 6 amps per foot with .73 volts. The fuel cell used thin perforated platinum electrodes. The pair of men said that partly solid electrolytes (the type of electrolyte that they used) work better than liquid electrolytes. 

Friedrich Wilhelm Ostwald: (1853-1939) Ostwald was a physical chemist who learned and understood how fuel cells work. Ostwald did experiments to find out everything he possibly could about the inside of a fuel cell in 1893. He also took what Grove said about the fuel cell and put into more detailed words. His research was a starting point for future researchers. 

Friedrich W. Jacques: (1855-1932) Jacques was an electrical engineer and a chemist. In 1896 he shocked America by making a carbon battery. A carbon battery has air interjected into its electrolyte and its electrodes are made of carbon. Jacques hypothesized that the carbon battery would have 82% efficiency, however it only had 8%. 

Emil Baur: (1873-1944) Baur worked with several other students to research as much as possible about fuel cells. He looked into several different types of fuel cells (Hydrogen-Oxygen is a example). The group also studied high temperature devices. 

Francis Thomas Bacon: Bacon researched alkali electrolyte fuel cells in the late 1930’s. In 1939 he built a fuel cell that used nickel gauze for its electrodes. The cell could stand pressure as high as 3,000, because of this it was used by the Royal Navy. It was also licensed for the Apollo Spacecraft, even though it was expensive.

Rechargeable Batteries
Parts of a Rechargeable Battery
In general the parts of a rechargeable battery are the same as the hydrogen oxygen fuel cell. But on closer inspection you can see that the type of chemicals that make up rechargeable battery is very different from the fuel cell. 

Ni-Cad
Fast Facts
Ni-cad batteries are actually called Nickel-Cadmium. The negative electrode is made of cadmium and the other electrode is nickel oxide. The electrolyte is potassium hydroxide.
Cadmium
Cadmium is a reactive metal used in batteries. Cadmium salt is used as coloring. 
Cadmium is yellow and it’s scientific symbol is CD. 
Memory Effect
Memory effect is like a sickness inside of a Nickel-Cadmium battery. It causes the battery to loose some of it’s electrical potential. In other words, the battery doesn’t have as much energy. Memory effect occurs when you consistently run the battery down part way then charge it up again. For example: If you put a Nickel?Cadmium battery into a flashlight use the battery power 1/4 0f the way down then charge it back up without using it all the way down for a couple weeks in a row then the capacity that hasn’t been used lately becomes unuseable. 

Nickel-Metal-Hydride
Concepts
Ni-HMs are not very efficient at extremely high and low temperatures and can’t be recycled. On the bright side they are less hazardous than other batteries. 
Replacing Nickel-Cadmium Batteries
Ni-HM batteries are cadmium free as NiCads obviously have lots. They also have less memory effect. Ni—Hms are much easier to maintain. 

Lead Acid Rechargeable Batteries
This is a rechargeable battery used in bigger machines, such as a car. It has 3 to 6 cells depending on the size of the battery. Each cell holds two sets of electrodes. The negative electrode is lead and the positive one is lead dioxide. The battery has an electrolyte of sulfuric acid. 

Volts, Amps, Watts, and Ohms 
Volts
 A Volt is the nickname for voltage. Volts are named for Allesandro Volta (see fuel cell history for details). To get more volts you need more current or amps. If you get more volts then you get more total power or watts. 
Watts
Watt is another name for electrical power. The equation to find watts is amps times volts. You use watts any time you turn on a lamp. Every lamp has a wattage, like 60 watt light bulb, 80 watt, 40 watts.
Ohms
Ohms is the measure of resistance. A common equation involving ohms is: ohms times volts equals amps. Ohms decrease as current increases. 
Amps
An amp is the measure of current. Amps times Amps equal volts divided by ohms. Increasing the voltage or decreasing the ohms will make the amperage go up. 

Summary
In conclusion, fuel cells and rechargeable batteries are both very useful. For example, fuel cells power things longer but rechargeable batteries power things quicker. Using them together may help in the future. 


BIBLIOGRAPHY

“Auto Talk” Business World Manila Oct 16, 2002.

Janies, D. Stanley.  Battery, World Book Encyclopedia, 1999.

"Fuel Cell,” World Book Encyclopedia Deluxe, 2001.

“Fuel Cell Origins.” 11-27-02 http://fuelcells.si.edu/origins/origins.htm

Benford, Gregory.  "Ohms Law,” World Book Encyclopedia, 2002.

Knapp, Brian. Zinc, Cadmium, Mercury. Connecticut, Groleir Education, 1996 pp. 4, 40-43, 45 

Metal Hydride. 11-22-03 http://www.battery-pack.com/nickel_metal_hydride.htm 

Nickel Cadmium. 11-22-03 www.battery-pack.com/nickel_cadmium.html 

Lead Acid Batteries. 11-15-03 www.hepi.com/basics/p b.html 

Nice, Karin. “How a Fuel Cell Works.” 10-29-02. http:// www.howstuffworks.com/fuelcell.hm

“What are Amps, Volts, Ohms, and Watts”. 3/5/o4 http://science.howstuffworks.com/question501.htm 

“ What is a Fuel Cell.” November 13, 2002. http:// www.fuelcells.org/whatis.htm

ACKNOWLEDGEMENTS
I would like to thank the following people for helping make my project possible:
* My parents for buying my materials and supporting me 
* My teachers for allowing me to miss some class to work on this project.
* I would especially like to thank Mr. Newkirk and Mrs. Helms for all of their hard work.
* Mr. McMillan for lending me the voltage probe and logger pro.
* I would also especially like to thank my Dad for all of this help this year and last. 
 


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