How Does Temperature Affect the Electrical Output of a Fuel Cell?

Researched by Kaitlin M.
2002-03



PURPOSE

The purpose of this experiment was to see if the electrical output of a fuel cell changed when operated at different temperatures.

I became interested in this idea when I was reading a newspaper article saying that auto manufactures might start making cars operated by fuel cells. I wondered if the fuel cell would be a good choice for a car since temperatures vary so much around the country. Florida is warm all year, but Alaska varies from cool to freezing.

The information gained from this experiment could help the drivers of America to decide if they really want a fuel cell car.


HYPOTHESIS

My hypothesis was that the fuel cell would work the best at 2°C. 

I based my hypothesis on Mrs. Patti Gustin, a high school science teacher. She said, "Reactions that release energy will work best at lower temperatures."  So that is why I thought that the fuel cell would work best at 2° C instead of 32°C, 22°C, or 12°C. 


EXPERIMENT DESIGN

The constants in this study were:

  • The multimeter used to measure the electrical output
  • The amount of trials (2 trials)
  • The type of stop watch
  • The electrical load on the fuel cell
  • The type of measurement
  • Fuel for fuel cell (hydrogen and oxygen)
  • The type and size of the fuel cell
  • Purity of water going into fuel cell (distilled)
  • Tool to separate hydrogen and oxygen (solar panel)
  • The type of light used on solar panel (lamp light)
  • Tool used to keep fuel cell cool when it is being charged (white wash cloth)


The manipulated variable was the temperature at which the fuel cell runs. 

The responding variable was how many volts the fuel cell produced. 

To measure the responding variable I used a multimeter.


MATERIALS
 
QUANTITY ITEM DESCRIPTION
1 hydrogen-oxygen fuel cell
1 multimeter (voltmeter)
1 room/bath room
1 distilled water
1 solar panel
1 refrigerator
1 big heater
1 mini heater
1 digital stopwatch
1 white washcloth
1 60-watt light


PROCEDURES

1. Get the fuel cell ready.
a. Take off the protector tubes on the side.
b. Use the syringe to pump water through the side of the cell.
c. Stop when you put one ml of water into the cell. 

2. Do test one at 2 degrees Celsius
a. Put 47 ml of water into the container that holds the gas containers.   Put the fuel cell into the location at 2°C for at least 1 hour.
b. Shine a lamp straight onto the middle of the solar panel, with the
     panel flat, to break the water a part until the gas containers have 
     gas bubbles coming out of the top. Cover the fuel cell covered 
     with a white washcloth to avoid accidentally heating up the fuel cell. 
c.   Start the stopwatch
d.  Use a voltmeter to measure the voltage output of the cell every
      minute. For 11 minutes. 

e.  Stop the stopwatch when the fuel cell runs out of hydrogen and   oxygen.
f. Conduct another trial. Use the same directions above except store the fuel cell at this temperature for 30 minutes prior to charging it.
3.Do test two at 12 degrees Celsius
     a.  Repeat steps 2a-2g.
     4. Do test three at 22 degrees Celsius
       a.  Repeat steps 2a-2g.
     5. Do test four at 32 degrees Celsius
a. Repeat steps 2a-2g.
     6. Graph the data
               a.  Find the mean for both trials at each temperature.
b. Find the overall mean for each temperature.
c. Make a graph of the minute-by-minute data for the mean output
     at each temperature. 


RESULTS

The original purpose of this experiment was to see if the electrical output of a fuel cell changed when operated at different temperatures.

The results of the experiment were that temperature made very little difference.  The average output varied from 0.71 volts to 0.74 volts which was less than a 5% difference, too little to say that a true difference existed.

At 2° and 12° the average output was 0.71 volts.  At 22° the average output was 0.73 and at 32° it was 0.74 volts.

See my table and graphs.


CONCLUSION

My hypothesis was that the fuel cell would work the best at 2°C.

The results indicate that this hypothesis should be rejected.  In fact the output at 2°C was one of the lowest, if any difference in voltage actually exists due to temperature, then it would appear that as temperature increased, so did voltage (but only a tiny bit.)

Because of the results of this experiment, I wonder if the purity of the water used in my fuel cell might affect output.  I also wonder if the large, powerful fuel cells built by the auto manufacturers work the same way as my little model.  I also wonder if the age of the fuel cell affects its output.  For example, does a brand new fuel cell act the same as one that has been used 1000 times.

If I were to conduct this project again I would run many more trials at each temperature level.  I would use three or more different fuel cells to see if all behaved the same.  I would also be extremely careful to make sure the fuel cell stayed at the correct temperature at all times during a certain trial. I would also try really hard to locate a true expert in fuel cell technology who could give me better ideas about how to proceed with my experiment.  As it was, I had to follow the instruction manual for my car and that might not have been the best approach.
 
 
Research Report

Introduction

Society has a need for large amounts of energy to power the tools we use, from refrigeration to stop lights to TV sets.  Power production often has the unfortunate side effect of creating pollution. This is especially true with batteries when the batteries are disposed of. Fuel cells do not have to be discarded. Fuel cells may be one way to avoid this problem.


How Fuel Cells Work

Fuel cells are similar to batteries in that they have the same basic parts inside, an electrolyte and two electrodes. Fuel cells never have to be replaced like batteries do.

Electrodes are the negative and positive metallic parts of the cell.  The negative electrode is called the cathode and the positive electrode is called the anode.

The electrolyte is a liquid that plays the part of an electron transporter. The electrons flow into the electrolyte and get moved to the other "electrical side" of the cell. 

The electrons flow through the anode to the electrolyte, through the cathode and into the device that is using power called the load. That cycle continues until the hydrogen and oxygen are gone. Then the cell is filled back up with hydrogen and oxygen. Fuel cells are very expensive. They are currently too expensive to use for anything except for NASA and other applications when cost is not a big issue. 


Problems

There are many problems with fuel cells, mainly because they are new technology and humans are still working out the bugs. One of the problems is obtaining hydrogen. Hydrogen works well, but is explosive. Hydrogen is so hard to find because it is exceedingly light and can be lost through the atmosphere. Most of the available hydrogen is buried underground.

Another problem with fuel cells is that to get hydrogen to cars you have to use a reformer. The reformer helps to get the hydrogen to the car, but it gets the hydrogen "dirty". Impure hydrogen makes the fuel cell less efficient. 


Hydrogen

Hydrogen is an element with atomic number of 1. It has 1 positively charged proton in its nucleus and 1 negatively charged electron. The universe is 99.88% hydrogen.

People use hydrogen for one basic reason. Ii is highly reactive with other chemicals. That means that scientists use hydrogen to make different types of chemicals. Water has 2 hydrogen atoms combined with one oxygen atom.

Hydrogen is very flammable. It was once used in blimps, but it explodes. It was used on May 6, 1937 in the Hindenburg and it exploded killing 1 person.

 It is also used to make methanol. It is used to make many different types of fertilizers.  Hydrogen is used in ammonia and many different products. 


Oxygen

Oxygen is an element with atomic number of 8. It has 8 positively charged protons in its nucleus and 8 electrons (-) obit the nucleus. Oxygen does not have a taste or a smell. It is also the most common element by volume and by mass on Earth. 
Oxygen is very reactive with many other chemicals. Some chemicals when they mix with oxygen either make a solid substance or a gas.  Some important things about oxygen are that it is in rocks, in all -living things, and forms 21% of the atmosphere. Also animals have to breathe oxygen to live.



History

Allesandro Volta (1745-1827) discovered the volt. Allesandro was born in Como, Italy.  He made something like a model of a battery.  When he did so, he produced about 1 volt so the volt was named after him. Volta also invented the voltaic pile. The voltaic pile is a type of battery. 

William Robert Grove (1811-1896) invented a better wet cell battery in 1830. He called it the Grove cell. It used the same tools inside the cell just made with different metals. The Grove cell made about 1.8 volts. He observed many of the qualities of the fuel cell, but he was at a disadvantage because nobody had ever actually made water by mixing hydrogen and oxygen.

Ludwig Mond (1839-1909) designed soda manufacturing and nickel refining. He and his partner did experiments with the fuel cell; they said that after the experiments they thought that only partially solid things worked the best in fuel cells. The electrodes were platinum and the fuel cell put out .73 volts.

Friedrich Wilhelm Ostwald (1853-1932) was a physical chemist. He understood how the fuel cell worked. He did experiments to see what happened inside of the fuel cell in 1893. He was able to give a more detailed description of a gas battery than William Robert Grove. His findings paved the road for future fuel cell researchers.

William W. Jacques (1855-1932) was an electrical engineer and a chemist. In 1896 he surprised the world by inventing a carbon battery.  In the carbon battery the air goes in the battery and reacts with the carbon electrode. William thought that the cell would be 82 percent efficient and it turned out to be only 8 percent efficient.

Emil Baur (1873-1944) studied different types of fuel cells.   He worked with several different high temperature devices in Switzerland. Emil did this work with various different students. 



Volts

Volts measure ability of an electric charge to give electricity to a device. Volts are really an electrical difference between points. They were named after the scientist Allesandro Volta.

In a household there is probably 110-240 volts being used. Electrons can go through the body doing damage if electricity is over 100 volts.



Temperature

Thermodynamics explains how heat and work in to energy. There are two laws. Law 1 says that energy is not created or destroyed. It is simply converted from other energy. Law 2 says that heat energy flows, only from warmer things toward cooler things. This theory explains why a heat engine is not totally efficient, because it gives off some of its heat.


Reactions

If energy is released during a chemical reaction then it is exothermic. If energy must be added then it is endothermic. As long as more heat is required than is being released then it is endothermic. If more heat is being released than is being added then it is exothermic. 



Summary

Fuel cells have many good factors but also a few faults. They would be very useful to our society because of how little they pollute. The first fuel cell car should be out soon.
 

Bibliography

"Allesandro Volta."11-6. www.theil.edu/digital\electronics/people/volta/ALLESANDRO%20Volta.htm 

"Auto Talk" Business World Manila Oct 16, 2002.

Bahnemann, Detlef Dr., et al. Fuel Cell Car & Experiment Kit Lab Manual. Stuttgart, Germany. Thames & Kosmos. 2000. Pp. 2-96

Bochm, F. Robert, Thermodynamics. World Book Encyclopedia. 1991.

"Fuel Cell," Microsoft Encarta Encyclopedia Deluxe. 2001.

"Fuel Cell Origins." 11-27-02 http://americanhistory.si.edu/csr/fuelcells/origins.htm 

Knapp, Brian BSC, PHD. Hydrogen and the Noble Gasses. Panbury, Connecticut.  Atlantic Europe Publishing Company Limited. 1996. 4,14,1,44,6 

Nice, Karin. "How a Fuel Cell Works." 10-29. http:// www.howstuffworks.com/fuelcell.hm 

Sharpe, Diana (executive editor) "Fuel cell," Illustrated Science Encyclopedia. 1997. 

"Tokyo Commercial Vehicle Show to Open in Late Oct." Jiji Press English News Service; Tokyo; Oct 12, 2002.

" What is a Fuel Cell." November 13, 2002. http:// www.fuelcells.org/whatis.htm

Wolfson, Richard. "Volts." World Book Encyclopedia. 2002.
 

ACKNOWLEDGEMENTS

I would like to thank a few people that helped me with this project. 
 

  • I would like to thank both of my parents, especially my Dad. They helped me so much by buying me all of my materials, helping me understand the fuel cell, and most of all having patience even though all of the pre-experiments.
  • I would also like to thank my science teacher for all of the tips and grading of papers and handouts. 
  • I would also like to thank Mrs. Carol Helms for the long hours of sitting in a boiler room, cutting papers, and help with computer problems are a few things she does. 
  • The last person I would like to thank is my homeroom teacher for all of those long hours in the computer lab. 

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